Semiconductor device and method

ABSTRACT

A method for forming a semiconductor device and a semiconductor device formed by the method are disclosed. In an embodiment, the method includes depositing a dummy dielectric layer on a fin extending from a substrate; depositing a dummy gate seed layer on the dummy dielectric layer; reflowing the dummy gate seed layer; etching the dummy gate seed layer; and selectively depositing a dummy gate material over the dummy gate seed layer, the dummy gate material and the dummy gate seed layer constituting a dummy gate.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional application of U.S. patent applicationSer. No. 16/050,234, filed on Jul. 31, 2018 (now U.S. Pat. No.10,868,137, issuing Dec. 15, 202), and entitled “Semiconductor Deviceand Method,” which patent application is incorporated herein byreference.

BACKGROUND

Semiconductor devices are used in a variety of electronic applications,such as, for example, personal computers, cell phones, digital cameras,and other electronic equipment. Semiconductor devices are typicallyfabricated by sequentially depositing insulating or dielectric layers,conductive layers, and semiconductor layers of material over asemiconductor substrate, and patterning the various material layersusing lithography to form circuit components and elements thereon.

The semiconductor industry continues to improve the integration densityof various electronic components (e.g., transistors, diodes, resistors,capacitors, etc.) by continual reductions in minimum feature size, whichallow more components to be integrated into a given area. However, asthe minimum features sizes are reduced, additional problems arise thatshould be addressed.

BRIEF DESCRIPTION OF THE DRAWINGS

Aspects of the present disclosure are best understood from the followingdetailed description when read with the accompanying figures. It isnoted that, in accordance with the standard practice in the industry,various features are not drawn to scale. In fact, the dimensions of thevarious features may be arbitrarily increased or reduced for clarity ofdiscussion.

FIG. 1 illustrates an example of a FinFET in a three-dimensional view,in accordance with some embodiments.

FIGS. 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14A, 14B, 15A, 15B, 16A,16B, 16C, 16D, 17A, 17B, 18A, 18B, 19A, 19B, 20A, 20B, 21A, 21B, 22A,22B, and 23 are cross-sectional views of intermediate stages in themanufacturing of FinFETs, in accordance with some embodiments.

DETAILED DESCRIPTION

The following disclosure provides many different embodiments, orexamples, for implementing different features of the invention. Specificexamples of components and arrangements are described below to simplifythe present disclosure. These are, of course, merely examples and arenot intended to be limiting. For example, the formation of a firstfeature over or on a second feature in the description that follows mayinclude embodiments in which the first and second features are formed indirect contact, and may also include embodiments in which additionalfeatures may be formed between the first and second features, such thatthe first and second features may not be in direct contact. In addition,the present disclosure may repeat reference numerals and/or letters inthe various examples. This repetition is for the purpose of simplicityand clarity and does not in itself dictate a relationship between thevarious embodiments and/or configurations discussed.

Further, spatially relative terms, such as “beneath,” “below,” “lower,”“above,” “upper” and the like, may be used herein for ease ofdescription to describe one element or feature's relationship to anotherelement(s) or feature(s) as illustrated in the figures. The spatiallyrelative terms are intended to encompass different orientations of thedevice in use or operation in addition to the orientation depicted inthe figures. The apparatus may be otherwise oriented (rotated 90 degreesor at other orientations) and the spatially relative descriptors usedherein may likewise be interpreted accordingly.

Various embodiments provide processes for forming improved dummy gates.For example, a dummy gate seed layer may be deposited over fins. Thedummy gate seed layer may be reflowed from above the fins into trenchesadjacent the fins. The dummy gate seed layer may be etched by ahalogen-gas etch. The halogen-gas etch may also terminate exposedsurface portions of a dummy dielectric layer disposed on the fins,between the fins and the dummy gate seed layer. An additional depositionprocess may be performed over the dummy gate seed layer and the dummydielectric layer. The additional deposition process may selectivelydeposit material on the dummy gate seed layer. In some embodiments, theadditional deposition process may deposit material on the dummy gateseed layer at a higher rate than on the dummy dielectric layer. Theresulting structure may then be planarized to form the dummy gates.

Performing a bottom-up deposition of the dummy gates prevents thebending of the fins and further prevents the formation of seams or voidsin the dummy gates. This improves device yield and reduces devicefailure.

FIG. 1 illustrates an example of a FinFET in a three-dimensional viewfor reference, in accordance with some embodiments. The FinFET comprisesa fin 58 on a substrate 50 (e.g., a semiconductor substrate). Isolationregions 56 are disposed in the substrate 50, and the fin 58 protrudesabove and from between neighboring isolation regions 56. Although theisolation regions 56 are described and illustrated as being separatefrom the substrate 50, as used herein the term “substrate” may be usedto refer to just the semiconductor substrate or a semiconductorsubstrate inclusive of the isolation regions 56. A gate dielectric layer92 is along sidewalls and over a top surface of the fin 58, and a gateelectrode 94 is over the gate dielectric layer 92. Source/drain regions82 are disposed in opposite sides of the fin 58 with respect to the gatedielectric layer 92 and gate electrode 94. FIG. 1 further illustratesreference cross-sections that are used in later figures. Cross-sectionA-A is along a longitudinal axis of the gate electrode 94 and in adirection, for example, perpendicular to the direction of current flowbetween the source/drain regions 82 of the FinFET. Cross-section B-B isperpendicular to the cross-section A-A and is along a longitudinal axisof the fin 58 and in a direction of, for example, a current flow betweenthe source/drain regions 82 of the FinFET. Cross-section C-C is parallelto the cross-section A-A and extends through one of the source/drainregions 82 of the FinFET. Subsequent figures refer to these referencecross-sections for clarity.

Some embodiments discussed herein are discussed in the context ofFinFETs formed using a gate-last process. In other embodiments, agate-first process may be used. Also, some embodiments contemplateaspects used in planar devices, such as planar FETs.

FIGS. 2 through 23 are cross-sectional views of intermediate stages inthe manufacturing of FinFETs, in accordance with some embodiments. FIGS.2 through 13 illustrate reference cross-section A-A illustrated in FIG.1 , except for multiple fins/FinFETs. In FIGS. 14A through 22B, figuresending with an “A” designation are illustrated along referencecross-section A-A illustrated in FIG. 1 and figures ending with a “B”designation are illustrated along a similar cross-section B-Billustrated in FIG. 1 , except for multiple fins/FinFETs. FIGS. 16C and16D are illustrated along reference cross-section C-C illustrated inFIG. 1 , except for multiple fins/FinFETs. FIG. 23 illustrates referencecross-section B-B illustrated in FIG. 1 , except for multiplegates/FinFETs.

In FIG. 2 , a substrate 50 is provided. The substrate 50 may be asemiconductor substrate, such as a bulk semiconductor, asemiconductor-on-insulator (SOI) substrate, or the like, which may bedoped (e.g., with a p-type dopant or an n-type dopant) or undoped. Thesubstrate 50 may be a wafer, such as a silicon wafer. Generally, an SOIsubstrate is a layer of a semiconductor material formed on an insulatorlayer. The insulator layer may be, for example, a buried oxide (BOX)layer, a silicon oxide layer, or the like. The insulator layer isprovided on a substrate which is typically a silicon or glass substrate.Other substrates, such as a multi-layered or gradient substrate may alsobe used. In some embodiments, the semiconductor material of thesubstrate 50 may include silicon; germanium; a compound semiconductorincluding silicon carbide, gallium arsenic, gallium phosphide, indiumphosphide, indium arsenide, and/or indium antimonide; an alloysemiconductor including SiGe, GaAsP, AnnAs, AlGaAs, GalnAs, GaInP,and/or GaInAsP; or combinations thereof.

The substrate 50 has a first region 50A and a second region 50B. Thefirst region 50A may be for forming n-type devices, such as NMOStransistors, e.g., n-type FinFETs. The second region 50B may be forforming p-type devices, such as PMOS transistors, e.g., p-type FinFETs.The first region 50A may be physically separated from the second region50B (as illustrated by divider 51), and any number of device features(e.g., other active devices, doped regions, isolation structures, etc.)may be disposed between the first region 50A and the second region 50B.In some embodiments, both the first region 50A and the second region 50Bare used to form the same type of devices, such as both regions beingfor n-type devices or p-type devices.

In FIG. 3 , fins 52 are formed in the substrate 50. The fins 52 aresemiconductor strips. In some embodiments, the fins 52 may be formed inthe substrate 50 by etching trenches in the substrate 50. The etchingmay be one or more of any acceptable etch process, such as a reactiveion etch (RIE), neutral beam etch (NBE), the like, or a combinationthereof. The etching may be anisotropic. Please note, although the fins52 are illustrated as having linear edges, the fins 52 may be rounded orhave any other suitable shape. The fins 52 may have a fin-to-fin spacingof between about 5 nm and about 50 nm, such as about 20 nm. However, insome embodiments, the fins 52 may have a fin-to-fin spacing of greaterthan about 50 nm or less than about 5 nm.

In FIG. 4 , an insulation material 54 is formed over the substrate 50and between neighboring fins 52. The insulation material 54 may be anoxide, such as silicon oxide, a nitride, the like, or a combinationthereof, and may be formed by a high density plasma chemical vapordeposition (HDP-CVD), a flowable CVD (FCVD) (e.g., a CVD-based materialdeposition in a remote plasma system, followed by a post-deposition cureto convert the material to another material, such as an oxide), thelike, or a combination thereof. Other insulation materials formed by anyacceptable process may be used. In the illustrated embodiment, theinsulation material 54 is silicon oxide formed by an FCVD process. Ananneal process may be performed once the insulation material is formed.In an embodiment, the insulation material 54 is formed such that excessinsulation material covers the fins 52.

In FIG. 5 , a planarization process is applied to the insulationmaterial 54. In some embodiments, the planarization process includes achemical mechanical polish (CMP), an etch-back process, combinationsthereof, or the like. The planarization process exposes the fins 52. Topsurfaces of the fins 52 and the insulation material 54 are level afterthe planarization process is complete.

In FIG. 6 , the insulation material 54 is recessed to form shallowtrench isolation (STI) regions 56. The insulation material 54 isrecessed such that fins 58 in the first region 50A and in the secondregion 50B protrude from between neighboring STI regions 56. Further,the top surfaces of the STI regions 56 may have a flat surface asillustrated, a convex surface, a concave surface (such as dishing), or acombination thereof. The top surfaces of the STI regions 56 may beformed flat, convex, and/or concave by using an appropriate etch. TheSTI regions 56 may be recessed using an acceptable etching process, suchas one that is selective to the material of the insulation material 54.For example, a chemical oxide removal using a plasma-less gaseousetching process (e.g., an etching process using hydrogen fluoride (HF)gas, ammonia (NH₃) gas, or the like), a remote plasma assisted dry etchprocess (e.g., a process using hydrogen (H₂), nitrogen trifluoride(NF₃), and ammonia by-products, or the like), or dilute hydrofluoric(dHF) acid may be used.

A person having ordinary skill in the art will readily understand thatthe process described with respect to FIGS. 2 through 6 is just oneexample of how the fins 58 may be formed. In some embodiments, adielectric layer may be formed over a top surface of the substrate 50;trenches may be etched through the dielectric layer; homoepitaxialstructures may be epitaxially grown in the trenches; and the dielectriclayer may be recessed such that the homoepitaxial structures protrudefrom the dielectric layer to form the fins 58. In some embodiments,heteroepitaxial structures may be used for the fins 52. For example, thefins 52 in FIG. 5 may be recessed, and a material different from thefins 52 may be epitaxially grown in their place. In an even furtherembodiment, a dielectric layer may be formed over a top surface of thesubstrate 50; trenches may be etched through the dielectric layer;heteroepitaxial structures may be epitaxially grown in the trenchesusing a material different from the substrate 50; and the dielectriclayer may be recessed such that the heteroepitaxial structures protrudefrom the dielectric layer to form the fins 58. In some embodiments wherehomoepitaxial or heteroepitaxial structures are epitaxially grown, theepitaxially grown materials may be in situ doped during growth. This mayobviate prior and subsequent implantations, although in situ andimplantation doping may be used together. Still further, it may beadvantageous to epitaxially grow a material in an NMOS region differentfrom the material in a PMOS region. In various embodiments, the fins 58may be formed from silicon germanium (Si_(x)Ge_(1-x), where x may be inthe range of 0 to 1), silicon carbide, pure or substantially puregermanium, a III-V compound semiconductor, a II-VI compoundsemiconductor, or the like. For example, the available materials forforming III-V compound semiconductor include, but are not limited to,InAs, AlAs, GaAs, InP, GaN, InGaAs, InAlAs, GaSb, AlSb, AlP, GaP, andthe like.

In additional embodiments, appropriate wells (not separatelyillustrated) may be formed in the fins 58, the fins 52, and/or thesubstrate 50. In some embodiments, a P well may be formed in the firstregion 50A and an N well may be formed in the second region 50B. In someembodiments, a P well or an N well may be formed in both the firstregion 50A and the second region 50B.

In embodiments in which different well types are formed, the differentimplant steps for the first region 50A and the second region 50B may beachieved using a photoresist or other masks (not separatelyillustrated). For example, a photoresist may be formed over the fins 58and the STI regions 56 in the first region 50A and the second region50B. The photoresist is patterned to expose the second region 50B of thesubstrate 50, such as a PMOS region. The photoresist may be formed byusing a spin-on technique and may be patterned using acceptablephotolithography techniques. Once the photoresist is patterned, ann-type impurity implant is performed in the second region 50B, and thephotoresist may act as a mask to substantially prevent n-type impuritiesfrom being implanted into the first region 50A, such as an NMOS region.The n-type impurities may be phosphorus, arsenic, or the like implantedin the region to a concentration of equal to or less than 10¹⁸ cm⁻³,such as between about 10¹⁷ cm⁻³ and about 10¹⁸ cm⁻³. After the implant,the photoresist is removed, such as by an acceptable ashing process.

Following the implanting of the second region 50B, a second photoresistis formed over the fins 58 and the STI regions 56 in the first region50A and the second region 50B. The photoresist is patterned to exposethe first region 50A of the substrate 50, such as the NMOS region. Thephotoresist may be formed by using a spin-on technique and may bepatterned using acceptable photolithography techniques. Once thephotoresist is patterned, a p-type impurity implant may be performed inthe first region 50A, and the photoresist may act as a mask tosubstantially prevent p-type impurities from being implanted into thesecond region 50B, such as the PMOS region. The p-type impurities may beboron, BF₂, or the like implanted in the region to a concentration ofequal to or less than 10¹⁸ cm⁻³, such as between about 10¹⁷ cm⁻³ andabout 10¹⁸ cm⁻³. After the implant, the photoresist may be removed, suchas by an acceptable ashing process.

After the implants of the first region 50A and the second region 50B, ananneal may be performed to activate the p-type and/or n-type impuritiesthat were implanted. In some embodiments, the grown materials ofepitaxial fins may be in situ doped during growth, which may obviate theimplantations. According to some embodiments, in situ and implantationdoping may be used together.

In FIG. 7 , a dummy dielectric layer 60 is formed on the fins 58. Thedummy dielectric layer 60 may be, for example, silicon oxide, siliconnitride, a combination thereof, or the like, and may be deposited orthermally grown according to acceptable techniques. The dummy dielectriclayer 60 may have a thickness T1 of between about 10 Å and about 100 Å,such as about 40 Å. As illustrated in FIG. 7 , the dummy dielectriclayer 60 may be selectively formed on the fins 58 and may not be formedon the STI regions 56.

In FIG. 8 , a dummy gate material 63 is formed over the dummy dielectriclayer 60 and the STI regions 56. In some embodiments, the dummy gatematerial 63 may be formed of an amorphous silicon (a-Si) material. Thedummy gate material 63 may be formed by any suitable process, such as achemical vapor deposition (CVD) process, an atomic layer deposition(ALD) process, a low pressure chemical vapor deposition (LPCVD) process,or the like. The formation of the dummy gate material 63 may includedepositing a silicon seed layer (not separately illustrated), and thengrowing additional silicon on the silicon seed layer. In accordance withsome embodiments, the dummy gate material 63 is referred to as a dummygate seed layer. Precursors used to deposit the dummy gate material 63may include SiH₃—N((CH—(CH₃)₂)₂, disilane (Si₂H₆), monosilane (SiH₄),combinations thereof, or the like. The dummy gate material 63 may befree from other elements such as germanium (Ge), n-type impurities (suchas phosphorous (P) and arsenic (As)), and p-type impurities (such asboron (B) and indium (In)), or may include some of these elements.

In embodiments in which disilane is used to grow the dummy gate material63, the temperature may be in the range between about 300° C. and about450° C. In embodiments in which monosilane is used to grow the dummygate material 63, the temperature may be in the range between about 400°C. and about 600° C. Depending on the temperature, the growth rate ofthe dummy gate material 63, and other process conditions, the dummy gatematerial 63 may be an amorphous silicon layer or a polysilicon layer. Asillustrated in FIG. 8 , the dummy gate material 63 may be a conformallayer and may have a relatively uniform thickness along top surfaces ofthe dummy dielectric layer 60 and the STI regions 56 and alongsidesurfaces of the dummy dielectric layer 60. The dummy gate material 63may have a thickness T2 of between about 1 nm and about 20 nm, such asabout 5 nm.

In FIG. 9 , the dummy gate material 63 is reflowed from above the fins58 into trenches alongside the fins 58. The dummy gate material 63 maybe reflowed by heating the substrate 50, by circulating heated gas overthe top surface of the dummy gate material 63, by combinations thereof,or by any other suitable method. In some embodiments, the reflow isperformed at a temperature in the range of between about 450° C. andabout 600° C., such as about 470° C. The reflow may last between about 3minutes and about 2 hours, depending on the temperature, with a highertemperature corresponding to a shorter reflow time and a lowertemperature corresponding to a longer reflow time. During the reflow,process gases such as nitrogen (N₂) or hydrogen (H₂) may be introduced.The dummy gate material 63 may be reflowed at a pressure of less thanabout 100 Torr, such as between about 1 mTorr and about 90 Torr. Thedummy gate material 63 may be reflowed such that a thickness T3 of thedummy gate material 63 on the top surface of the dummy dielectric layer60 is between about 0.1 nm and about 20 nm, such as about 5 nm.Following the reflow, a concentration of hydrogen (H) in the dummy gatematerial 63 may be between about 0.1 percent by weight and about 2percent by weight, or less than about 2 percent by weight. In someembodiments, the dummy gate material 63 may have a hydrogenconcentration of less than about 2×10²⁰ atoms/cm³ after reflowing thedummy gate material 63.

In FIG. 10 , the dummy gate material 63 is etched in order to expose atleast a portion of the dummy dielectric layer 60. The dummy gatematerial 63 may be etched by any suitable process, such as ahalogen-based gas etch (e.g., a halogen-based plasma etch) or the like.The etching process may use a suitable gas. The etching process may usea halogen-containing gas, such as a gas containing chlorine (Cl₂),fluorine (F₂), bromine (Br₂), iodine (I₂), combinations thereof, or thelike. The etching gas may react with the exposed portions of the dummydielectric layer 60 to terminate the exposed portions of the dummydielectric layer 60, forming a halogen-terminated dummy dielectric layer61. The halogen-terminated dummy dielectric layer 61 may act as apassivation layer. In some embodiments, the etching gas may also reactwith exposed portions of the dummy gate material 63 to terminate exposedportions of the dummy gate material 63, forming a halogen-terminatedlayer on the exposed portion of the dummy gate material 63 (notseparately illustrated).

The dummy gate material 63 may be etched such that a height H2 of thedummy gate material 63 is greater than about ten percent of a height H1of the dummy dielectric layer 60 in combination with thehalogen-terminated dummy dielectric layer 61. For example, the height H1may be between about 30 nm and about 100 nm, such as about 35 nm. Theheight H2 may be between about 3 nm and about 99 nm, such as about 30nm. The height H2 may be between about 10 percent and about 99 percentof the height H1, such as about 80 percent of the height H1. In someembodiments, the height H2 may be greater than about 10 percent of theheight H1.

In FIG. 11 , an additional dummy gate material 63′ is deposited on thedummy gate material 63 by an additional deposition process, such as CVD,ALD, or the like. The additional deposition process may be selective anddeposition may only occur on the dummy gate material 63, not on thehalogen-terminated dummy dielectric layer 61. As such, the additionaldummy gate material 63′ may be deposited over the dummy gate material 63of FIG. 10 in a bottom-up process. In some embodiments, the additionaldummy gate material 63′ may be deposited over both the dummy gatematerial 63 and the halogen-terminated dummy dielectric layer, but mayoccur at a higher rate on the dummy gate material 63 than thehalogen-terminated dummy dielectric layer 61. In some embodiments, thehalogen-terminated dummy dielectric layer 61 may have an incubation time(e.g., a time required for the additional dummy gate material 63′ toform on a surface of the layer after exposure to the additionaldeposition process) that is greater than an incubation time for thedummy gate material 63 by more than about 40 minutes or more than about5 minutes.

In FIG. 12 , the additional dummy gate material 63′ is further depositedby the additional deposition process and then planarized to form a dummygate layer 62. The dummy gate layer 62 may be planarized by any suitableplanarization process, such as by a chemical mechanical planarization(CMP) process, grinding, an etch-back planarization process, or thelike. The dummy gate layer 62 may have a height H3 of between about 60nm and about 190 nm, such as about 100 nm. The dummy gate layer 62 maybe formed of the same or similar materials as the dummy gate material63. For example, the dummy gate layer 62 may be formed of an amorphoussilicon (a-Si) material throughout.

Forming the dummy gate layer 62 by depositing the dummy gate material63, reflowing the dummy gate material 63, etching the dummy gatematerial 63 and terminating the dummy dielectric layer 60, andperforming additional deposition of the additional dummy gate material63′ on the dummy gate material 63 (e.g., forming the dummy gate layer 62by a bottom-up deposition process) reduces the formation of seams orvoids between the fins 58 and reduces the aspect ratio of trenchesbetween the fins 58. This process also reduces bending of the fins 58.For example, a delta fin-to-fin spacing (e.g., a variation or a changein fin-to-fin spacing) after forming the dummy gate layer may be lessthan about 6 nm, such as about 0.55 nm, or about 0.29 nm. Bothseams/voids formed in the dummy gate layer 62 and bending of the fins 58may cause problems with the deposition of a replacement gate (discussedbelow in reference to FIGS. 20A and 20B), and forming the dummy gatelayer 62 by the above-described methods advantageously reduces theseproblems.

In some embodiments, the above-described bottom-up deposition processmay be used in forming transistors in some regions on the substrate 50,and conventional processes may be used in forming transistors in otherregions on the substrate 50. Only the transistors formed by theabove-described bottom-up deposition process may experience the benefitsof the bottom-up process. Moreover, the halogen-terminated dummydielectric layer 61 may only be present in transistors formed by thebottom-up process. In contrast, transistors formed by conventionalprocess may include a dummy dielectric layer which is nothalogen-terminated.

In FIG. 13 , a mask layer 64 is formed over the dummy gate layer 62. Themask layer 64 may be deposited over the dummy gate layer 62 by anysuitable method, such as CVD, plasma-enhanced CVD (PECVD), low pressureCVD (LPCVD), or the like. The mask layer 64 may include, for example,silicon nitride (e.g., Si₃N₄), silicon oxide (SiO₂), silicon oxynitride(Si₂N₂O), or the like.

FIGS. 14A through 22B illustrate various additional steps in themanufacturing of embodiment devices. FIGS. 14A through 22B illustratefeatures in either of the first region 50A and the second region 50B.For example, the structures illustrated in FIGS. 14A through 22B may beapplicable to both the first region 50A and the second region 50B.Differences (if any) in the structures of the first region 50A and thesecond region 50B are described in the text accompanying each figure.

In FIGS. 14A and 14B, the mask layer 64 may be patterned usingacceptable photolithography and etching techniques to form masks 74. Thepattern of the masks 74 then may be transferred to the dummy gate layer62 by an acceptable etching technique to form dummy gates 72. In someembodiments, the pattern of the masks 74 may also be transferred to thedummy dielectric layer 60 and/or the halogen-terminated dummy dielectriclayer 61 (not separately illustrated). The dummy gates 72 coverrespective channel regions of the fins 58. The pattern of the masks 74may be used to physically separate each of the dummy gates 72 fromadjacent dummy gates. The dummy gates 72 may also have a lengthwisedirection substantially perpendicular to the lengthwise direction ofrespective epitaxial fins 52/58.

Further in FIGS. 14A and 14B, gate seal spacers 80 may be formed onexposed surfaces of the dummy gates 72, the masks 74, and/or the fins58. A thermal oxidation or a deposition followed by an anisotropic etchmay form the gate seal spacers 80.

After the formation of the gate seal spacers 80, implants for lightlydoped source/drain (LDD) regions (not explicitly illustrated) may beperformed. In the embodiments with different device types, similar tothe implants discussed above in FIG. 6 , a mask, such as a photoresist,may be formed over the first region 50A, while exposing the secondregion 50B, and appropriate type (e.g., p-type) impurities may beimplanted into the exposed fins 58 in the second region 50B. The maskmay then be removed. Subsequently, a mask, such as a photoresist, may beformed over the second region 50B while exposing the first region 50A,and appropriate type (e.g., n-type) impurities may be implanted into theexposed fins 58 in the first region 50A. The mask may then be removed.The n-type impurities may be the any of the n-type impurities previouslydiscussed, and the p-type impurities may be the any of the p-typeimpurities previously discussed. The lightly doped source/drain regionsmay have a concentration of impurities of from about 10¹⁵ cm⁻³ to about10¹⁶ cm⁻³. An anneal may be used to activate the implanted impurities.

In FIGS. 15A and 15B, gate spacers 86 are formed on the gate sealspacers 80 along sidewalls of the dummy gates 72 and the masks 74. Thegate spacers 86 may be formed by conformally depositing a material andsubsequently anisotropically etching the material. The material of thegate spacers 86 may be silicon nitride, SiCN, a combination thereof, orthe like.

In FIGS. 16A and 16B epitaxial source/drain regions 82 are formed in thefins 58. The epitaxial source/drain regions 82 are formed in the fins 58such that each dummy gate 72 is disposed between respective neighboringpairs of the epitaxial source/drain regions 82. In some embodiments thatepitaxial source/drain regions 82 may extend into the fins 52. In someembodiments, the gate spacers 86 are used to separate the epitaxialsource/drain regions 82 from the dummy gates 72 by an appropriatelateral distance so that the epitaxial source/drain regions 82 do notshort out subsequently formed gates of the resulting FinFETs.

The epitaxial source/drain regions 82 in the first region 50A, e.g., theNMOS region, may be formed by masking the second region 50B, e.g., thePMOS region, and etching source/drain regions of the fins 58 in thefirst region 50A form recesses in the fins 58. Then, the epitaxialsource/drain regions 82 in the first region 50A are epitaxially grown inthe recesses. The epitaxial source/drain regions 82 may include anyacceptable material, such as appropriate for n-type FinFETs. Forexample, if the fin 58 is silicon, the epitaxial source/drain regions 82in the first region 50A may include silicon, SiC, SiCP, SiP, or thelike. The epitaxial source/drain regions 82 in the first region 50A mayhave surfaces raised from respective surfaces of the fins 58 and mayhave facets.

The epitaxial source/drain regions 82 in the second region 50B, e.g.,the PMOS region, may be formed by masking the first region 50A, e.g.,the NMOS region, and etching source/drain regions of the fins 58 in thesecond region 50B are etched to form recesses in the fins 58. Then, theepitaxial source/drain regions 82 in the second region 50B areepitaxially grown in the recesses. The epitaxial source/drain regions 82may include any acceptable material, such as appropriate for p-typeFinFETs. For example, if the fin 58 is silicon, the epitaxialsource/drain regions 82 in the second region 50B may comprise SiGe,SiGeB, Ge, GeSn, or the like. The epitaxial source/drain regions 82 inthe second region 50B may also have surfaces raised from respectivesurfaces of the fins 58 and may have facets.

The epitaxial source/drain regions 82 and/or the fins 58 may beimplanted with dopants to form source/drain regions, similar to theprocess previously discussed for forming lightly doped source/drainregions, followed by an anneal. The source/drain regions may have animpurity concentration of between about 10¹⁹ cm⁻³ and about 10²¹ cm⁻³.The n-type and/or p-type impurities for source/drain regions may be anyof the impurities previously discussed. In some embodiments, theepitaxial source/drain regions 82 may be in situ doped during growth.

As a result of the epitaxy processes used to form the epitaxialsource/drain regions 82 in the first region 50A and the second region50B, upper surfaces of the epitaxial source/drain regions have facetswhich expand laterally outward beyond a sidewalls of the fins 58. Insome embodiments, these facets cause adjacent source/drain regions 82 ofa same finFET to merge as illustrated by FIG. 16C. In other embodiments,adjacent source/drain regions 82 remain separated after the epitaxyprocess is completed as illustrated by FIG. 16D.

In FIGS. 17A and 17B, an ILD 88 is deposited over the structureillustrated in FIGS. 16A and 16B. The ILD 88 may be formed of adielectric material or a semiconductor material, and may be deposited byany suitable method, such as CVD, plasma-enhanced CVD (PECVD), or FCVD.Dielectric materials may include phosphosilicate glass (PSG),borosilicate glass (BSG), boron-doped phosphosilicate glass (BPSG),undoped silicate glass (USG), or the like. Semiconductor materials mayinclude amorphous silicon (a-Si), silicon germanium (Si_(x)Ge_(1-x),where x may be between approximately 0 and 1), pure germanium, or thelike. Other insulation or semiconductor materials formed by anyacceptable process may be used. In some embodiments, a contact etch stoplayer (CESL, not separately illustrated), is disposed between the ILD 88and the epitaxial source/drain regions 82, the hard mask 74, and thegate spacers 86.

In FIGS. 18A and 18B, a planarization process, such as a CMP, may beperformed to level the top surface of the ILD 88 with the top surfacesof the dummy gates 72. The planarization process may also remove themasks 74 on the dummy gates 72, and portions of the gate seal spacers 80and the gate spacers 86 along sidewalls of the masks 74. After theplanarization process, top surfaces of the dummy gates 72, the gate sealspacers 80, the gate spacers 86, and the ILD 88 are level. Accordingly,the top surfaces of the dummy gates 72 are exposed through the ILD 88.

In FIGS. 19A and 19B, the dummy gates 72 and portions of thehalogen-terminated dummy dielectric layer 61 directly underlying theexposed dummy gates 72 are removed in an etching step(s), so thatrecesses 90 are formed. In some embodiments, the dummy gates 72 areremoved by an anisotropic dry etch process. For example, the etchingprocess may include a dry etch process using reaction gas(es) thatselectively etch the dummy gates 72 without etching the ILD 88 or thegate spacers 86. Each recess 90 exposes a channel region of a respectivefin 58. Each channel region is disposed between neighboring pairs of theepitaxial source/drain regions 82. During the removal, thehalogen-terminated dummy dielectric layer 61 may be used as an etch stoplayer when the dummy gates 72 are etched. The halogen-terminated dummydielectric layer 61 may then be removed after the removal of the dummygates 72.

In FIGS. 20A and 20B, a gate dielectric layer 92, a work function layer93, and gate electrodes 94 are formed for replacement gates. The gatedielectric layer 92 is deposited conformally in the recesses 90, such ason the top surfaces and the sidewalls of the fins 58 and on sidewalls ofthe gate seal spacers 80/gate spacers 86. The gate dielectric layer 92may also be formed on top surface of the ILD 88. In accordance with someembodiments, the gate dielectric layer 92 comprises silicon oxide(SiO₂), silicon nitride (Si₃N₄), or multilayers thereof. In someembodiments, the gate dielectric layer 92 is a high-k dielectricmaterial, and in these embodiments, the gate dielectric layer 92 mayhave a k value greater than about 7.0, and may include a metal oxide ora silicate of Hf, Al, Zr, La, Mg, Ba, Ti, Pb, and combinations thereof.The formation methods of the gate dielectric layer 92 may includemolecular beam deposition (MBD), ALD, PECVD, and the like.

Further in FIGS. 20A and 20B, conductive material is formed to fill therecesses 90. The conductive material may include one or more barrierlayers, work function layers, and/or work function tuning layers to tunethe work function of the subsequently formed gate electrodes. In anembodiment, the work function layer 93 is deposited over the gatedielectric layer 92. The work function layer 93 may be ametal-containing material such as Al, TiC, TiN, combinations thereof, ormulti-layers thereof.

The gate electrodes 94 are deposited over the work function layer 93 andfill the remaining portions of the recesses 90. The gate electrodes 94may be a metal-containing material such as TiN, TaN, TaC, Co, Ru, Al,combinations thereof, or multi-layers thereof. After the filling of thegate electrodes 94, a planarization process, such as a CMP, may beperformed to remove the excess portions of the gate dielectric layer 92,the work function layer 93, and the gate electrodes 94, which excessportions are over the top surface of the ILD 88. The remaining portionsof the gate electrodes 94, the work function layer 93, and the gatedielectric layer 92 thus form replacement gates of the resultingFinFETs. The gate electrodes 94, the work function layer 93, and thegate dielectric layer 92 may be collectively referred to as a “gate” ora “gate stack.” The gate and the gate stacks may extend along sidewallsof a channel region of the fins 58.

The formation of the gate dielectric layer 92 in the first region 50Aand the second region 50B may occur simultaneously such that the gatedielectric layer 92 in each region are formed from the same materials.Similarly, the formation of the work function layer 93 and the formationof the gate electrodes 94 in the first region 50A and the second region50B may each occur simultaneously such that the work function layer 93and the gate electrodes 94 in each region are formed from the samematerials as the work function layer 93 and the gate electrodes 94 inthe other region. In some embodiments, the gate dielectric layers 92,the work function layers 93, and the gate electrodes 94 in each regionmay be formed by distinct processes, such that the gate dielectriclayers 92, the work function layers 93, and the gate electrodes 94 ineach region may be different materials. Various masking steps may beused to mask and expose appropriate regions when using distinctprocesses.

In FIGS. 21A and 21B, an ILD 108 is deposited over the ILD 88. In anembodiment, the ILD 108 is a flowable film formed by a flowable CVDmethod. In some embodiments, the ILD 108 is formed of a dielectricmaterial such as PSG, BSG, BPSG, USG, or the like, and may be depositedby any suitable method, such as CVD and PECVD.

In FIGS. 22A and 22B, a gate contact 110 and source/drain contacts 112are formed through the ILD 108 and the ILD 88. Openings for thesource/drain contacts 112 (not separately illustrated) are formedthrough the ILD 108 and the ILD 88, and openings for the gate contact110 (not separately illustrated) are formed through the ILD 108. Theopenings may be formed using acceptable photolithography and etchingtechniques. Optionally, prior to formation of the gate contact 110 andthe source/drain contacts 112, a silicide contact (not separatelyillustrated) may be formed. The silicide contact may comprise titanium,nickel, cobalt, or erbium, and may be used to reduce the Schottkybarrier height of the gate contact 110 and the source/drain contacts112. However, other metals, such as platinum, palladium, and the like,may also be used. The silicidation may be performed by blanketdeposition of an appropriate metal layer, followed by an annealing stepwhich causes the metal to react with the underlying exposed silicon.Un-reacted metal is then removed, such as with a selective etch process.The thickness of the silicide contact may be between about 5 nm andabout 50 nm.

The gate contact 110 and the source/drain contacts 112 may be formed ofconductive materials such as Al, Cu, W, Co, Ti, Ta, Ru, TiN, TiAl,TiAlN, TaN, TaC, NiSi, CoSi, combinations of these, or the like,although any suitable material may be used. The material of the gatecontact 110 and the source/drain contacts 112 may be deposited into theopenings in the ILD 108 and the ILD 88 using a deposition process suchas sputtering, chemical vapor deposition, electroplating, electrolessplating, or the like, to fill and/or overfill the openings. Once filledor overfilled, any deposited material outside of the openings may beremoved using a planarization process such as chemical mechanicalpolishing (CMP).

The gate contact 110 is physically and electrically connected to thegate electrode 94, and the source/drain contacts 112 are physically andelectrically connected to the epitaxial source/drain regions 82. FIGS.22A and 22B illustrate the gate contact 110 and the source/draincontacts 112 in a same cross-section; however, in other embodiments, thegate contact 110 and the source/drain contacts 112 may be disposed indifferent cross-sections. Further, the position of the gate contact 110and the source/drain contacts 112 in FIGS. 22A and 22B are merelyillustrative and not intended to be limiting in any way. For example,the gate contact 110 may be vertically aligned with the fin 52 asillustrated or may be disposed at a different location on the gateelectrode 94. Furthermore, the source/drain contacts 112 may be formedprior to, simultaneously with, or after forming the gate contacts 110.As illustrated in FIGS. 22A and 22B, at least a portion of thehalogen-terminated dummy dielectric layer 61 may remain on the fin 58.

FIG. 23 illustrates a FinFET device in the first region 50A and a FinFETdevice in the second region 50B. As illustrated in FIG. 23 , the FinFETdevices in the first region 50A and the second region 50B the same orsimilar to one another and may each be formed by the steps discussedabove in reference to FIGS. 14A through 22B. The FinFET devices in thefirst region 50A may be formed simultaneously with the FinFET devices inthe second region 50B, or separately from the FinFET devices in thesecond region 50B.

Many transistors may be formed across the surface of the substrate 50.In some embodiments, the bottom-up process described above may be usedto form transistors in some regions of the substrate 50, andconventional processes may be used to form transistors in other regionsof the substrate 50. As a result, only the regions including transistorsformed by the bottom-up process may experience the benefits of thebottom-up process, and the halogen-terminated dummy dielectric layer 61may only be present in the regions in which transistors are formed bythe bottom-up process. The regions including transistors formed byconventional process may include conventional dummy dielectric layers,which are not halogen-terminated.

Forming the dummy gate layer 62 according to the bottom-up processdescribed above results in several advantages. For example, thebottom-up process reduces bending of the fins 58. This process alsoprevents seams or voids from being formed in the dummy gate layer 62. Asa result, the dummy gate layer 62 may be completely removed beforeforming the gate stack without leaving any residue or residual material.This leads to improved device performance as well as increased deviceyield.

In accordance with an embodiment, a method includes depositing a dummydielectric layer on a fin extending from a substrate; depositing a dummygate seed layer on the dummy dielectric layer; reflowing the dummy gateseed layer; etching the dummy gate seed layer; and selectivelydepositing a dummy gate material over the dummy gate seed layer, thedummy gate material and the dummy gate seed layer forming a dummy gate.In an embodiment, etching the dummy gate seed layer exposes a portion ofthe dummy dielectric layer. In an embodiment, etching the dummy gateseed layer forms a terminated surface on the dummy dielectric layer inthe exposed portion of the dummy dielectric layer. In an embodiment, thedummy gate material is deposited at a first rate on the dummy gate seedlayer, the dummy gate material is deposited at a second rate on theterminated surface of the dummy dielectric layer, and the first rate isgreater than the second rate. In an embodiment, the method furtherincludes removing the dummy gate to form a recess; and forming areplacement gate in the recess. In an embodiment, removing the dummygate further includes removing at least a portion of the dummydielectric layer, and another portion of the dummy dielectric layerincluding the terminated surface remains after removing the dummy gate.In an embodiment, etching the dummy gate seed layer includes ahalogen-based plasma etch. In an embodiment, the dummy gate seed layerhas a hydrogen concentration of less than 2×10²⁰ atoms/cm³ after thereflowing the dummy gate seed layer. In an embodiment, the dummy gateseed layer is deposited by atomic layer deposition (ALD) or chemicalvapor deposition (CVD). In an embodiment, the dummy gate includesamorphous silicon (a-Si). In an embodiment, the dummy gate seed layer isreflowed at a temperature greater than 470° C. for a time greater thanthree minutes and at a pressure of less than 100 Torr.

In accordance with another embodiment, a method includes depositing adummy dielectric layer on a fin extending from a substrate; depositing afirst dummy gate material on the dummy dielectric layer; reflowing thefirst dummy gate material; etching the first dummy gate material and thedummy dielectric layer, the etching the dummy dielectric layer forming aterminated dummy dielectric layer; and depositing a second dummy gatematerial over the first dummy gate material to form a dummy gate, thesecond dummy gate material being selectively deposited on the firstdummy gate material. In an embodiment, the method further includesetching the dummy gate and the dummy dielectric layer to form a recess,at least a portion of the terminated dummy dielectric layer remainingafter etching the dummy gate and the dummy dielectric layer; and forminga gate stack in the recess. In an embodiment, the etching includes ahalogen-based gas etching. In an embodiment, a surface of the dummydielectric layer is exposed by the etching the first dummy gate materialand the exposed surface of the dummy dielectric layer is terminated bythe etching to form the terminated dummy dielectric layer. In anembodiment, the substrate includes a plurality of fins, and a variationin a fin-to-fin spacing of the plurality of fins is less than 6 nm afterforming the dummy gate.

In accordance with yet another embodiment, a semiconductor deviceincludes a gate stack over a semiconductor substrate; a gate spacerdisposed on sidewalls of the gate stack; and a dielectric layer disposedbetween the semiconductor substrate and the gate spacer, the dielectriclayer including a halogen-terminated surface. In an embodiment, thehalogen-terminated surface includes chlorine-terminated silicon dioxide.In an embodiment, the semiconductor substrate includes one or more fins.In an embodiment, the semiconductor device further includes a secondgate stack over the semiconductor substrate; a second gate spacerdisposed on sidewalls of the second gate stack; and a second dielectriclayer disposed between the semiconductor substrate and the second gatespacer, the second dielectric layer being not halogen-terminated.

The foregoing outlines features of several embodiments so that thoseskilled in the art may better understand the aspects of the presentdisclosure. Those skilled in the art should appreciate that they mayreadily use the present disclosure as a basis for designing or modifyingother processes and structures for carrying out the same purposes and/orachieving the same advantages of the embodiments introduced herein.Those skilled in the art should also realize that such equivalentconstructions do not depart from the spirit and scope of the presentdisclosure, and that they may make various changes, substitutions, andalterations herein without departing from the spirit and scope of thepresent disclosure.

What is claimed is:
 1. A semiconductor device comprising: a gate stackover a semiconductor substrate; a first fin extending from thesemiconductor substrate, the first fin having a first top surface andfirst sidewalls, wherein the gate stack extends along and is in directphysical contact with the first top surface and the first sidewalls ofthe first fin; a gate spacer disposed on second sidewalls of the gatestack; and a dielectric layer disposed between the semiconductorsubstrate and the gate spacer, the dielectric layer comprising ahalogen-terminated surface, wherein the dielectric layer has a firstplanar surface parallel to the semiconductor substrate and wherein thegate spacer has a second planar surface in direct physical contact withthe first planar surface, wherein the dielectric layer extends along andis in direct physical contact with the first top surface of the firstfin at a constant thickness.
 2. The semiconductor device of claim 1,wherein the halogen-terminated surface comprises chlorine-terminatedsilicon dioxide.
 3. The semiconductor device of claim 1, furthercomprising: a second gate stack over the semiconductor substrate; asecond gate spacer disposed on sidewalls of the second gate stack; and asecond dielectric layer disposed between the semiconductor substrate andthe second gate spacer, wherein the second dielectric layer is nothalogen-terminated.
 4. The semiconductor device of claim 1, furthercomprising a source/drain region in the semiconductor substrate adjacentthe gate stack, wherein the dielectric layer extends from the gate stackto the source/drain region.
 5. The semiconductor device of claim 1,wherein the halogen-terminated surface comprises fluorine.
 6. Thesemiconductor device of claim 1, wherein the halogen-terminated surfacecomprises bromine.
 7. The semiconductor device of claim 1, wherein thedielectric layer has a thickness of 40 angstroms and thehalogen-terminated surface comprises iodine.
 8. The semiconductor deviceof claim 1, further comprising a second fin extending from thesemiconductor substrate, the second fin adjacent to the first fin.
 9. Asemiconductor device comprising: a fin extending from a semiconductorsubstrate, the fin having a top surface and sidewalls; a gate stack overthe fin, wherein the gate stack is in direct physical contact with thetop surface and the sidewalls of the fin, the gate stack having a firstsurface facing towards the semiconductor substrate; a source/drainregion in the fin adjacent the gate stack; and a halogen-terminateddielectric layer extending form the source/drain region to the gatestack over the top surface of the fin, wherein the halogen-terminateddielectric layer has a constant thickness across the top surface of thefin, the halogen-terminated dielectric layer having a second surfacethat is coplanar with the first surface, the second surface facingtowards the semiconductor substrate.
 10. The semiconductor device ofclaim 9, wherein the halogen-terminated dielectric layer compriseschlorine-terminated silicon dioxide.
 11. The semiconductor device ofclaim 9, further comprising a gate spacer adjacent the gate stack, thehalogen-terminated dielectric layer extending from the fin to the gatespacer.
 12. The semiconductor device of claim 11, wherein sidewalls ofthe halogen-terminated dielectric layer are coterminous with sidewallsof the gate spacer.
 13. The semiconductor device of claim 9, wherein thegate stack comprises a gate dielectric layer in physical contact withthe fin and the halogen-terminated dielectric layer, a work functionlayer over the gate dielectric layer, and a fill material over the workfunction layer.
 14. The semiconductor device of claim 9, furthercomprising a second fin extending from the semiconductor substrate, thesecond fin adjacent to the fin.
 15. A semiconductor device comprising: afin extending from a semiconductor substrate; a dielectric layerextending along a top surface of the fin and in direct physical contactwith the top surface of the fin, wherein the dielectric layer has aconstant thickness across the top surface, the dielectric layercomprising a halogen-terminated surface facing away from thesemiconductor substrate; a gate stack extending along and in directphysical contact with the top surface and sidewalls of the fin; and agate spacer over the fin adjacent the gate stack.
 16. The semiconductordevice of claim 15, wherein the dielectric layer extends from the fin tothe gate spacer.
 17. The semiconductor device of claim 15, furthercomprising a source/drain region in the fin, wherein the dielectriclayer is in physical contact with the source/drain region.
 18. Thesemiconductor device of claim 17, wherein the dielectric layer is inphysical contact with the gate stack.
 19. The semiconductor device ofclaim 15, wherein the sidewalls of the fin are free from the dielectriclayer.
 20. The semiconductor device of claim 15, wherein the dielectriclayer comprises chlorine-terminated silicon dioxide.